CN decoration of dibenzofuran modified biphenyl for high triplet energy host for blue phosphorescent organic light-emitting diodes

A strongly electron deficient and high triplet energy host for blue emitters was developed by decorating a dibenzofuran modified biphenyl backbone structure with multiple CN units. Two hosts, 6,6′-bis(6-cyanodibenzo[b,d]furan-4-yl)-[1,1′-biphenyl]-3,3′-dicarbonitrile(CNDBF1) and 2,2′-bis(6-cyanodibenzo[b,d]furan-4-yl)-[1,1′-biphenyl]-4,4′-dicarbonitrile(CNDBF2), were derived from the CN decoration strategy for application in blue organic light-emitting diodes requiring high triplet energy host. They showed high triplet energy above 2.79 eV and acted as the electron transport type host based on the strong electron deficiency. The mixture of the CNDBF1 and CNDBF2 hosts with a hole transport type 3,3′-di(9H-carbazol-9-yl)-1,1′-biphenyl host performed as the exciplex host of a blue phosphor and accomplished high external quantum efficiency of 22.7% in the blue phosphorescent organic light-emitting diodes.     

Maskless metal patterning by meniscus-confined electrochemical etching and its application in organic field-effect transistors

Conductive micropatterns is an essential part for operation of electronic devices in both industrial and academic fields. Conventional mask-based photolithography and vacuum deposition are inadequate to meet the demands of convenience and simplicity due to their complicated operation, costly instrumentations and relatively low resolution (for vacuum deposition). Development of simple and efficient mask-less fabrication techniques of conductive micropatterns is highly expected. Here we report a facile meniscus-confined electrochemical etching (MCEE) approach to fabricate metal micropatterns with resolution down to at least 1.0 μm. Both the applied bias and the moving velocity directly influence the patterning resolution. MCEE process is developed to fabricate source and drain electrodes in organic transistors on both rigid and flexible substrates. Being a maskless direct writing method, the width and morphology of the etched channel can be easily modulated by the bias and the velocity. The organic transistor with top-contact configuration presents better electrical performance with device on/off ratio of 1.1 × 10⁵ and maximum carrier mobility of 1.07 cm²V⁻¹s⁻¹, which implies that MCEE operation doesn't result in the degradation of the already deposited semiconducting film. This mask-less MCEE approach provides a potential complementary to conventional mask-based techniques for the fabrication of microscale metal patterns.     

基于3D打印技术制造柔性传感器研究进展

与传统的涂覆、沉积等加工手段相比，使用3D打印技术可制造复杂立体功能结构的传感器，将3D打印与柔性传感技术结合可以促进未来生物医疗、人工智能等领域的发展。本文介绍了国内外基于3D打印技术制造柔性传感器的最新进展，其中包括聚酰亚胺等多种基底材料、纳米金属等多种打印传感材料；按照熔融沉积、黏弹性墨水沉积、粉末烧结熔化、还原光聚合和材料喷射的制造原理分别阐述了多种传感器的材料选择、成型特点，并对制造方法进行总结分析。虽然3D打印制造柔性传感器件存在着缺乏行业标准及多种类打印材料等问题，但经过不断创新与发展，3D打印将成为柔性传感领域极佳的制造手段。     

煤矿提升机制动系统电控装置设计

为了确保矿井安全提升，设计了煤矿提升机制动系统电控装置。基于液压制动特性，研究了电控装置硬件和软件系统，硬件方面主要分析了传感器装置、人机交互界面、恒减速制动控制卡、PLC和电源的选型和设计；软件方面主要研究了系统状态显示和故障处理功能流程、安全制动功能流程及人机界面的主界面设计。研究为确保煤矿提升机制动系统安全可靠运行提供了技术支持。     

一种双边自行车停车装置的设计

针对共享单车停放困难影响交通秩序的现状,迫切需要研发自行车停车装置。设计了一种“摩天轮”式新型双边立式自行车停车装置,由机械执行机构和控制系统两大部分组成。前者通过大转矩步进电机和蜗轮蜗杆减速箱带动圆盘转动形成旋转执行机构,可提供6个自行车车位;后者利用32位闪存微控制器STM32系列单片机来处理停车装置运行过程中产生的数据,实现用户在存取自行车过程中6个车位顺畅地切换以及定位。该装置具有空间利用率高、存取简便快捷、美观防盗等特点,为解决共享单车的停放管理问题提供一种可参考的解决方案。     

摇篮式五坐标加工中心C轴转台旋转故障原因分析与处理

针对HS664RT,摇篮式五坐标加工中心力矩电动机驱动的C轴转台故障,介绍了故障排查、处理方法和力矩电动机相位角同步设置步骤。     

无线电综合测试仪校准装置的研究及其不确定度分析

This calibration device of radio comprehensive tester is studied and established in this paper. It solves the verification and calibration of a large number of general-purpose radio comprehensive testers. The calibration device consists of four calibration sub- systems and calibration software system, including RF generator, audio generator, audio analyzer and RF analyzer. It also researches on the configuration of standard equipment and analyzes the uncertainty of the calibration devices, ensuring accurate and reliable val- ue transfer.     

Thermal Management Enables Bright and Stable Perovskite Light-Emitting Diodes

The performance of lead-halide perovskite light-emitting diodes (LEDs) has increased rapidly in recent years. However, most reports feature devices operated at relatively small current densities (<500 mA cm⁻²) with moderate radiance (<400 W sr⁻¹ m⁻²). Here, Joule heating and inefficient thermal dissipation are shown to be major obstacles toward high radiance and long lifetime. Several thermal management strategies are proposed in this work, such as doping charge-transport layers, optimizing device geometry, and attaching heat spreaders and sinks. Combining these strategies, high-performance perovskite LEDs are demonstrated with maximum radiance of 2555 W sr⁻¹ m⁻², peak external quantum efficiency (EQE) of 17%, considerably reduced EQE roll-off (EQE > 10% to current densities as high as 2000 mA cm⁻²), and tenfold increase in operational lifetime (when driven at 100 mA cm⁻²). Furthermore, with proper thermal management, a maximum current density of 2.5 kA cm⁻² and an EQE of ≈1% at 1 kA cm⁻² are shown using electrical pulses, which represents an important milestone toward electrically driven perovskite lasers.     

Research on optimization design of PWR flow distribution device based on numerical simulation

ABSTRACT

In the lower chamber of pressurized water reactor (PWR), the flow distribution device is the core module to distribute coolant into the core. It has complex structure and numerous design parameters. Therefore, it has important theoretical and practical significance to optimize the device. The mesh independence verification, turbulence model selection, and data processing all can influence the numerical simulation results of the lower chamber, in order to research the influence, a numerical simulation method based on the original model of CNP1000 reactor lower chamber is proposed in this paper. In the method, an optimization design method of flow distribution device is established based on surrogate model. The main design variables and optimization objectives are determined based on the device’s structure and function characteristics. And then it respectively adopts Kriging algorithm and multi-objective genetic algorithm to establish a surrogate model of flow distribution device and optimize it globally. Finally, the optimal design variables are obtained. Compared with the device’s performance before optimization, the after optimization has smaller total pressure loss and more uniform flow. The effectiveness and practicability of proposed optimization design method can be verified.     

某两自由度弹药提升装置的建模、实验及仿真研究

弹药自动装填系统的研究已经成为火炮武器平台中机械系统设计的关键和难点,基于一种两自由度弹药提升装置,并根据该装置的工作原理构造数学模型,搭建实验平台,建立PID控制回路,同时创建该模型的虚拟样机模型,使用动力学仿真软件Recurdyn和Matlab/Simulink进行联合仿真,并通过实验与仿真的数据进行对比,验证该装置的可行性和所采用控制的有效性。